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Cement & Concrete Technology Home > FAQs> ASR

Q: How can I test for alkali-silica reactivity (ASR)?

A: Alkali-silica reactivity is the process in which certain minerals (mostly glass type silica) in the presence of moisture are broken down by the highly alkaline environment of concrete producing a gel that expands creating tensile forces in the concrete matrix which cause cracking of the concrete. The cracking then allows more water to infiltrate into the concrete creating more gel, more expansion etc. Ultimately the concrete fails or disintegrates.

Table: Test Methods for Alkali-Silica Reactivity (Source: Farny and Kerkhoff, 2007)

Test Name

Purpose

Type of Test

Duration of Test

Comments

ASTM C 227,
Potential alkali-reactivity of cement-aggregate combinations (mortar-bar method)

To test the susceptibility of cement-aggregate combinations to expansive reactions involving alkalies

Mortar bars stored over water at 37.8°C (100°F) and high relative humidity

Varies: first measurement at 14 days, then 1, 2, 3, 4, 6, 9, and 12 months; every 6 months afterthat as necessary

Test may not produce significant expansion, especially for carbonate aggregate. Long test duration. Expansions may not be from AAR.

ASTM C 289,
Potential alkali-silica reactivity of aggregates

To determine potential reactivity of siliceous aggregates Sample reacted with alkaline solution at 80°C (176°F). 24 hours Quick results. Some aggregates give low expansions even though they have high silica content. Not reliable.

ASTM C 294,
Constituents of natural mineral aggregates

To give descriptive nomenclature for themore common or important natural minerals—an aid in determining their performance

Visual identification

Short duration—as long as it takes to visually examine the sample

These descriptions are used to characterize naturally-occurring minerals that makeup common aggregate sources.

ASTM C 295,
Petrographic examination of aggregates for concrete

To outline petrographic examination procedures for aggregates—an aid indetermining their performance Visual and microscopic examination of prepared samples—sieve analysis, microscopy, scratch or acid tests Short duration—visual examination does not involve long test periods Usually includes opticalmicroscopy. Also may include XRD analysis, differential thermal analysis, or infrared spectroscopy—see ASTM C 294 for descriptive nomenclature.

ASTM C 342,
Potential volume change of cement-aggregate combinations

To determine the potential ASR expansion of cement-aggregate combinations Mortar bars stored in water at 23°C (73.4°F) 52 weeks Primarily used for aggregates from Oklahoma, Kansas, Nebraska, and Iowa.

ASTM C 441,
Effectiveness of mineral admixtures or GBFS inpreventing excessive expansion of concrete due to alkali-silica reaction

To determine effectiveness of supplementary cementing materials in controlling expansion from ASR Mortar bars—using Pyrex glass as aggregate—stored over water at 37.8°C (100°F) and high relative humidity Varies: first measurement at 14 days, then 1, 2, 3, 4, 5, 9, and 12 months; every 6 months after that as necessary Highly reactive artificial aggregate may not represent real aggregate conditions. Pyrex contains alkalies.

ASTM C 856,
Petrographic examination of hardened concrete

To outline petrographic examination procedures for hardened concrete—useful in determining condition or performance Visual (unmagnified) and microscopic examination of prepared samples Short duration — includes preparation of samples and visual and microscope examination Specimens can be examined with stereomicroscopes,polarizing microscopes, metallographic  microscopes, and scanning electron microscope.

ASTM C 856 (AASHTO T 299),
Annex uranyl- acetate treatment procedure

To identify products of ASR in hardened concrete Staining of a freshly-exposed concrete surface and viewing under UV light Immediate results Identifies small amounts of ASR gel whether they cause expansion or not.Opal, a natural aggregate, and carbonated paste can glow—interpret results accordingly.Tests must be supplemented by petrographic examination and physical tests for determining concrete expansion
Los Alamos staining method (Powers 1999) To identify products of ASR in hardened concrete. Staining of a freshly-exposedconcrete surface with two different reagents. Immediate results

ASTM C 1260 (AASHTO T303),
Potential alkali reactivity of aggregates (mortar-bar method)

To test the potential for deleterious alkali-silica reaction of aggregate in mortar bars Immersion of mortar bars in alkaline solution at 80°C (176°F) 16 days Very fast alternative to C 227. Useful for slowly reacting aggregates or those that produce expansion late in the reaction.

ASTM C 1293,
Determination of length change of concrete due to alkali-silica reaction (concrete prism test)

To determine the potential ASR expansion of cement-aggregate combinations. Concrete prisms stored over water at 38°C (100.4°F) Varies: first measurement at 7 days, then 28and 56 days, then 3,6,9,and 12 months; every 6 months as after that as necessary Preferred method of assessment. Best represents the field. Requires long test duration for meaningful results. Use as a supplement to C 227,C 295, C 289, and C 1260. Similar to CSA A23.2-14A.
ASTM C 1567, Potential alkali-silica reactivity of combinations of cementitious materials and aggregate (accelerated mortar-bar method)
To test the potential for deleterious alkali-silica reaction of cementitious materials and aggregate combinations in mortar bars
Immersion of mortar bars in alkaline solution at 80°C (176°F)
16 days
Very fast alternative to C 1293. Allows for evaluation of effectiveness of supplementary cementitious materials.

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